Tridecane
(Synonyms: 正十三烷) 目录号 : GC61711
Tridecane是含有13个碳原子的短链脂肪族烃。Tridecane是从PiperaduncumL的精油中分离出来的一种挥发性油成分。Tridecane也是一种由褐纹臭蝽释放出来的物质。
Cas No.:629-50-5
Sample solution is provided at 25 µL, 10mM.
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Quality Control & SDS
- View current batch:
- Purity: >99.00%
- COA (Certificate Of Analysis)
- SDS (Safety Data Sheet)
- Datasheet
Tridecane is a short chain aliphatic hydrocarbon containing 13 carbon atoms. Tridecane is an volatile oil component isolated from essential oil of Piper aduncum L. Tridecane is a stress compound released by the brown marmorated stink bugs stress compound[1][2].
[1]. Pallavi Mohekar, et al. Influence of Winemaking Processing Steps on the Amounts of (E)-2-Decenal and Tridecane as Off-Odorants Caused by Brown Marmorated Stink Bug (Halyomorpha halys). J Agric Food Chem. 2017 Feb 1;65(4):872-878. [2]. Motoi Yamashita, et al. The effect of pressure on the phase transition behavior of tridecane, pentadecane, and heptadecane: a Fourier transform infrared spectroscopy study. J Chem Phys. 2011 Apr 14;134(14):144503.
| Cas No. | 629-50-5 | SDF | |
| 别名 | 正十三烷 | ||
| Canonical SMILES | CCCCCCCCCCCCC | ||
| 分子式 | C13H28 | 分子量 | 184.36 |
| 溶解度 | 储存条件 | Store at -20°C | |
| General tips | 请根据产品在不同溶剂中的溶解度选择合适的溶剂配制储备液；一旦配成溶液，请分装保存，避免反复冻融造成的产品失效。 储备液的保存方式和期限：-80°C 储存时，请在 6 个月内使用，-20°C 储存时，请在 1 个月内使用。 为了提高溶解度，请将管子加热至37℃，然后在超声波浴中震荡一段时间。 |
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| Shipping Condition | 评估样品解决方案：配备蓝冰进行发货。所有其他可用尺寸：配备RT，或根据请求配备蓝冰。 | ||
| 制备储备液 | |||
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1 mg | 5 mg | 10 mg |
| 1 mM | 5.4242 mL | 27.1209 mL | 54.2417 mL |
| 5 mM | 1.0848 mL | 5.4242 mL | 10.8483 mL |
| 10 mM | 0.5424 mL | 2.7121 mL | 5.4242 mL |
| 第一步：请输入基本实验信息（考虑到实验过程中的损耗，建议多配一只动物的药量） | ||||||||||
| 给药剂量 | mg/kg |  |
动物平均体重 | g | |
每只动物给药体积 | ul | |
动物数量 | 只 |
| 第二步：请输入动物体内配方组成（配方适用于不溶于水的药物；不同批次药物配方比例不同，请联系GLPBIO为您提供正确的澄清溶液配方） | ||||||||||
| % DMSO % % Tween 80 % saline | ||||||||||
| 计算重置 | ||||||||||
计算结果:
工作液浓度： mg/ml；
DMSO母液配制方法： mg 药物溶于 μL DMSO溶液（母液浓度 mg/mL，
体内配方配制方法：取 μL DMSO母液，加入 μL PEG300，混匀澄清后加入μL Tween 80，混匀澄清后加入 μL saline，混匀澄清。
1. 首先保证母液是澄清的；
2.
一定要按照顺序依次将溶剂加入，进行下一步操作之前必须保证上一步操作得到的是澄清的溶液，可采用涡旋、超声或水浴加热等物理方法助溶。
3. 以上所有助溶剂都可在 GlpBio 网站选购。
Norprzewalsone A, a Rearranged Polycyclic Polyprenylated Acylphloroglucinol with a Spiro[cyclopentane-1,3'-tricyclo[7.4.0.01,6]Tridecane] Core from Hypericum przewalskii
J Org Chem 2022 May 20;87(10):6824-6831.PMID:35545918DOI:10.1021/acs.joc.2c00503.
Norprzewalsone A (1), a rearranged polyprenylated polycyclic acylphloroglucinol (PPAP) with a new carbon skeleton, along with a new congener, norprzewalsone B (2), were isolated from Hypericum przewalskii. Compound 1 possessed a new 5/6/5/6/6 pentacyclic ring system based on a spiro[cyclopentane-1,3'-tricyclo[7.4.0.01,6]Tridecane] core, which might be derived from the common [3.3.1]-type bicyclic polyprenylated acylphloroglucinol (BPAP) via the key retro-Claisen, intramolecular cyclization, and Diels-Alder cyclization reactions. Their structures and absolute configurations were confirmed by spectroscopic data, calculated 1D NMR data with DP4+ probability analyses, and electronic circular dichroism calculations and comparison. More significantly, compound 1 exhibited a moderate inhibitory effect on NO production in lipopolysaccharide-stimulated RAW264.7 cells.
Fortuneicyclidins A and B, Pyrrolizidine Alkaloids with a 7-Azatetracyclo[5.4.3.0.02,8]Tridecane Core, from Cephalotaxus fortunei
Org Lett 2021 Apr 2;23(7):2807-2810.PMID:33755492DOI:10.1021/acs.orglett.1c00738.
Fortuneicyclidins A (1) and B (2), a pair of epimeric pyrrolizidine alkaloids containing an unprecedented 7-azatetracyclo[5.4.3.0.02,8]Tridecane core, were isolated from the seeds of Cephalotaxus fortunei, along with two biogenetically relative known analogues, 3 and 4. The structures were determined by multiple spectral techniques and chemical derivatization methods. Compound 1 showed inhibitory activity against α-glucosidase.
Features of Self-Diffusion of Tridecane Molecules in a Porous Medium of Kaolinite Used as a Model of a Chemically Inert Membrane
Membranes (Basel) 2023 Feb 10;13(2):221.PMID:36837723DOI:10.3390/membranes13020221.
The present work focused on the experimental study of the specific features of self-diffusion of Tridecane molecules in macroporous kaolinite, which is used as a raw material for the production of chemically inert membranes. The measurements of self-diffusion coefficients by pulsed magnetic field gradient nuclear magnetic resonance (PMFG NMR) revealed an increased translational mobility of Tridecane molecules in kaolinite with incomplete filling of the pore space. This effect was accompanied by a sharp change in the slope of the Arrhenius plot of the self-diffusion coefficients of Tridecane molecules in kaolinite. An analysis of the diffusion spin echo decay in the tridecane-kaolinite system revealed a discrepancy between the experimental data and the theoretical predictions, considering the effect of the geometry of porous space on molecular mobility. It was shown that the experimental results could be interpreted in terms of a model of two phases of Tridecane molecules in the pores of kaolinite, in the gaseous and adsorbed state, coexisting under the fast-exchange conditions. Within the framework of the model, the activation energies of self-diffusion were calculated, which agreed satisfactorily with the experimental data. Additionally, the effects of the internal magnetic field gradients arising in a porous medium loaded with a gas or liquid on the data of the PFG NMR measurements were calculated. It was shown that the effect of magnetic field inhomogeneities on the measured self-diffusion coefficients of Tridecane in kaolinite is small and could be neglected.
Euphopias A-C: Three Rearranged Jatrophane Diterpenoids with Tricyclo[8.3.0.02,7]Tridecane and Tetracyclo[11.3.0.02,10.03,7]hexadecane Cores from Euphorbia helioscopia
Org Lett 2020 Oct 16;22(20):7820-7824.PMID:32991190DOI:10.1021/acs.orglett.0c02676.
Euphopias A-C (1-3), three rearranged jatrophane-type diterpenoids with tricyclo[8.3.0.02,7]Tridecane (1 and 2) and tetracyclo[11.3.0.02,10.03,7]hexadecane (3) cores, were isolated from Euphorbia helioscopia. Comprehensive spectroscopic analyses, quantum-chemical calculations, and X-ray diffractions were used to identify their structures. Compounds 1-3 could significantly inhibit NLRP3 inflammasome activation and block NLRP3 inflammasome-induced pyroptosis. Additionally, a mechanistic study revealed that 2 could ameliorate mitochondria damage, thereby interrupting NLRP3 inflammasome activation.
Pinacol Coupling Strategy for the Construction of the Bicyclo[6.4.1]Tridecane Framework of Schiglautone A
Org Lett 2017 Apr 7;19(7):1524-1526.PMID:28300417DOI:10.1021/acs.orglett.7b00288.
The synthesis of the tricyclic carbon framework of schiglautone A (1) is reported herein. The generation of the bicyclo[6.4.1]Tridecane 19 was accomplished via a SmI2-mediated pinacol coupling of dialdehyde 18. The side chain in 18 was introduced using a selective 1,4-addition. A further key step of the synthesis was the homologation of a Wieland-Miescher ketone derivative to establish the 7-membered ring.