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Ammonium iron(II) sulfate

(Synonyms: ammoniumironsulfate; ammoniumironsulfate(2:2:1); diammoniumferroussulfate; diammoniumironbis(sulphate); diammoniumironsulfate; ferrousdiammoniumdisulfate; Sulfuricacid,ammoniumiron(2+)salt(2:2:1); sulfuricacid,ammoniumiron(2++)salt(2:2:1)) 目录号 : GC20135

Ammonium iron(II) sulfate Chemical Structure

Cas No.:10045-89-3

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100g
¥300.00
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Chemical Properties

Cas No. 10045-89-3 SDF
别名 ammoniumironsulfate; ammoniumironsulfate(2:2:1); diammoniumferroussulfate; diammoniumironbis(sulphate); diammoniumironsulfate; ferrousdiammoniumdisulfate; Sulfuricacid,ammoniumiron(2+)salt(2:2:1); sulfuricacid,ammoniumiron(2++)salt(2:2:1)
分子式 Fe.(NH4)2.(SO4)2 分子量 284.05
溶解度 储存条件
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溶解性数据

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1 mg 5 mg 10 mg
1 mM 3.5205 mL 17.6025 mL 35.2051 mL
5 mM 0.7041 mL 3.5205 mL 7.041 mL
10 mM 0.3521 mL 1.7603 mL 3.5205 mL
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Research Update

The enzyme-induced formation of iron hybrid nanostructures with different morphologies

Nanoscale 2020 Jun 25;12(24):12917-12927.PMID:32525190DOI:10.1039/d0nr03142a.

A new synthesis method for tailor-made iron-hybrid nanoparticles has been carried out for the first time using enzymes, which directly induce the formation of inorganic iron species. The role of the protein was critical for the formation and morphology of the iron nanostructures and, depending on the enzyme, by simple mixing with Ammonium iron(II) sulfate at room temperature and under air, it was possible to obtain, for the first time, well stabilized superparamagnetic iron and iron oxide nanorods, nanosheets and nanorings or even completely amorphous non-magnetic iron structures in the protein network. These iron nanostructure-enzyme hybrids showed excellent results as heterogeneous catalysts in organic chemistry (chemoselective hydrogenation and C-C bonding formation) and environmental remediation processes.

Pencil it in: pencil drawn electrochemical sensing platforms

Analyst 2016 Jun 20;141(13):4055-64.PMID:27271819DOI:10.1039/c6an00402d.

Inspired by recent reports concerning the utilisation of hand drawn pencil macroelectrodes (PDEs), we report the fabrication, characterisation (physicochemical and electrochemical) and implementation (electrochemical sensing) of various PDEs drawn upon a flexible polyester substrate. Electrochemical characterisation reveals that there are no quantifiable electrochemical responses upon utilising these PDEs with an electroactive analyte that requires an electrochemical oxidation step first, therefore the PDEs have been examined towards the electroactive redox probes hexaammineruthenium(iii) chloride, potassium ferricyanide and Ammonium iron(II) sulfate. For the first time, characterisation of the number of drawn pencil layers and the grade of pencil are examined; these parameters are commonly overlooked when utilising PDEs. It is demonstrated that a PDE drawn ten times with a 6B pencil presented the most advantageous electrochemical platform, in terms of electrochemical reversibility and peak height/analytical signal. In consideration of the aforementioned limitation, analytes requiring an electrochemical reduction as the first process were solely analysed. We demonstrate the beneficial electroanalytical capabilities of these PDEs towards p-benzoquinone and the simultaneous detection of heavy metals, namely lead(ii) and cadmium(ii), all of which are explored for the first time utilising PDEs. Initially, the detection limits of this system were higher than desired for electroanalytical platforms, however upon implementation of the PDEs in a back-to-back configuration (in which two PDEs are placed back-to-back sharing a single connection to the potentiostat), the detection limits for lead(ii) and cadmium(ii) correspond to 10 μg L(-1) and 98 μg L(-1) respectively within model aqueous (0.1 M HCl) solutions.

Flow injection kinetic spectrophotometric determination of trace amounts of Se(IV) in seawater

Talanta 2005 May 15;66(4):1012-7.PMID:18970085DOI:10.1016/j.talanta.2005.01.029.

A simple, accurate, sensitive and selective flow injection catalytic kinetic spectrophotometric method for rapid determination of trace amounts of selenium is proposed in this paper. The proposed method is based on the accelerating effect of Se(IV) on the reaction of ethexlenediamine tetrecetic acid disodium salt (EDTA) and sodium nitrate with Ammonium iron(II) sulfate hexahydrate in acidic media. The absorbance intensity was registered in this reaction solution at 440nm. The calibration graph is linear in the range of 5x10(-9)-2x10(-7) and 2x10(-7)-2x10(-6)gml(-1). The detection limit is 2x10(-9)gml(-1). The relative standard deviation was 3.4% for 5x10(-8)gml(-1) Se(IV) (n=11), 2.7% for 5x10(-7)gml(-1) Se(IV) (n=11). This method is very simple, rapid and suitable for automatic and continuous analysis. The presented system has been applied successfully to determination of Se(IV) of seawater samples.

Bivoltametric titrations using electrodes with innovative geometry

Anal Bioanal Chem 1996 Sep;356(3-4):192-6.PMID:15048351DOI:10.1007/s0021663560192.

Electrodes with different surface areas were investigated for the determination of reversible, quasireversible, irreversible or electroinactive substrates. Two kinds of electrodes were constructed, a helical electrode with a given asymmetry and a platinum array electrode with a variable area. These electrodes were applied for the cerimetry of Ammonium iron(II) sulfate and for the bromatometry of various organic substances. The theoretically derived effects on the shape of the voltametric titration curve are verified experimentally. It is possible to sharpen one side of the peak and to broaden the other side, depending on the system and the side of the peak one is interested in. It is possible to improve the bivoltametric determination of hydroquinone, benzocaine and sulfaguanidine by bromatometry by the directed employment of electrodes of different areas. For the bromatometric determination of electrochemically irreversible substrates the use of the electrode geometries proposed is a way to obtain a sharp bend and a steep decrease of titration curves with low values of the constant current which is a basic requirement for the accuracy.