Bismuth subcarbonate
(Synonyms: Bismuth carbonate oxide) 目录号 : GC61825
Bismuth subcarbonate (Bismuth carbonate oxide) 是一种典型的铋基半导体，广泛应用于抗菌、传感器、超级电容器和光催化剂。Bismuth subcarbonate 保护胃溃疡免受胃酸进一步侵蚀。
Cas No.:10-4-5892
Sample solution is provided at 25 µL, 10mM.
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Quality Control & SDS
- View current batch:
- Purity: >99.00%
- COA (Certificate Of Analysis)
- SDS (Safety Data Sheet)
- Datasheet
Bismuth subcarbonate (Bismuth carbonate oxide) is a typical Bi-based semiconductor that is widely applied as antibacterial, sensors, super capacitors, and photocatalysts. Bismuth subcarbonate protects the gastric ulcer from further erosion by gastric acid[1][2].
References:
[1]. Chenmin Xu, et al. Bismuth Subcarbonate with Designer Defects for Broad-Spectrum Photocatalytic Nitrogen Fixation. ACS Appl Mater Interfaces. 2018 Aug 1;10(30):25321-25328.
[2]. Rimsha Ali, et al. Milk-Alkali Syndrome. StatPearls [Internet]. 2021 Jan.
| Cas No. | 10-4-5892 | SDF | |
| 别名 | Bismuth carbonate oxide | ||
| Canonical SMILES | [Bi][Bi](C(O[O])=O)([O])=O | ||
| 分子式 | CBi2O5 | 分子量 | 509.97 |
| 溶解度 | 储存条件 | 4°C, protect from light | |
| General tips | 请根据产品在不同溶剂中的溶解度选择合适的溶剂配制储备液；一旦配成溶液，请分装保存，避免反复冻融造成的产品失效。 储备液的保存方式和期限：-80°C 储存时，请在 6 个月内使用，-20°C 储存时，请在 1 个月内使用。 为了提高溶解度，请将管子加热至37℃，然后在超声波浴中震荡一段时间。 |
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| Shipping Condition | 评估样品解决方案：配备蓝冰进行发货。所有其他可用尺寸：配备RT，或根据请求配备蓝冰。 | ||
| 制备储备液 | |||
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1 mg | 5 mg | 10 mg |
| 1 mM | 1.9609 mL | 9.8045 mL | 19.609 mL |
| 5 mM | 0.3922 mL | 1.9609 mL | 3.9218 mL |
| 10 mM | 0.1961 mL | 0.9804 mL | 1.9609 mL |
| 第一步：请输入基本实验信息（考虑到实验过程中的损耗，建议多配一只动物的药量） | ||||||||||
| 给药剂量 | mg/kg |  |
动物平均体重 | g | |
每只动物给药体积 | ul | |
动物数量 | 只 |
| 第二步：请输入动物体内配方组成（配方适用于不溶于水的药物；不同批次药物配方比例不同，请联系GLPBIO为您提供正确的澄清溶液配方） | ||||||||||
| % DMSO % % Tween 80 % saline | ||||||||||
| 计算重置 | ||||||||||
计算结果:
工作液浓度： mg/ml；
DMSO母液配制方法： mg 药物溶于 μL DMSO溶液（母液浓度 mg/mL，
体内配方配制方法：取 μL DMSO母液，加入 μL PEG300，混匀澄清后加入μL Tween 80，混匀澄清后加入 μL saline，混匀澄清。
1. 首先保证母液是澄清的；
2.
一定要按照顺序依次将溶剂加入，进行下一步操作之前必须保证上一步操作得到的是澄清的溶液，可采用涡旋、超声或水浴加热等物理方法助溶。
3. 以上所有助溶剂都可在 GlpBio 网站选购。
Thermal Decomposition of Nanostructured Bismuth subcarbonate
Materials (Basel) 2020 Sep 25;13(19):4287.PMID:32992863DOI:10.3390/ma13194287.
Nanostructured (BiO)2CO3 samples were prepared, and their thermal decomposition behaviors were investigated by thermogravimetric analysis under atmospheric conditions. The method of preparation and Ca2+ doping could affect the morphologies of products and quantity of defects, resulting in different thermal decomposition mechanisms. The (BiO)2CO3 nanoplates decomposed at 300-500 °C with an activation energy of 160-170 kJ/mol. Two temperature zones existed in the thermal decomposition of (BiO)2CO3 and Ca-(BiO)2CO3 nanowires. The first one was caused by the decomposition of (BiO)4(OH)2CO3 impurities and (BiO)2CO3 with surface defects, with an activation energy of 118-223 kJ/mol, whereas the second one was attributed to the decomposition of (BiO)2CO3 in the core of nanowires, with an activation energy of 230-270 kJ/mol for the core of (BiO)2CO3 nanowires and 210-223 kJ/mol for the core of Ca-(BiO)2CO3 nanowires. Introducing Ca2+ ions into (BiO)2CO3 nanowires improved their thermal stability and accelerated the decomposition of (BiO)2CO3 in the decomposition zone.
Indium doped Bismuth subcarbonate nanosheets for efficient electrochemical reduction of carbon dioxide to formate in a wide potential window
J Colloid Interface Sci 2022 Oct 15;624:261-269.PMID:35660895DOI:10.1016/j.jcis.2022.05.054.
Electrochemical carbon dioxide (CO2) reduction reaction (E-CO2RR) to formate with high selectivity driven by renewable electricity is one of the most promising routes to carbon neutrality. Herein, we developed a novel indium (In)-doped Bismuth subcarbonate (BOC) nanosheets (BOC-In-x NSs) through transformation of In-doped bismuth (Bi) nanoblocks (Bi-In-x NBs). The BOC-In-0.1 NSs achieved a maximum Faraday efficiency of formate (FEformate) nearly 100% with high stability (22 h) and an appreciable average FEformate of 93.5% in a wide potential window of 450 mV. The experimental and theoretical calculations indicate that the incorporation of In into BOC nanosheets enhanced the adsorption of CO2 and the intermediates during the process of E-CO2RR, and reduced the energy barrier for the formation of formate.
Bismuth subcarbonate with Designer Defects for Broad-Spectrum Photocatalytic Nitrogen Fixation
ACS Appl Mater Interfaces 2018 Aug 1;10(30):25321-25328.PMID:29969006DOI:10.1021/acsami.8b05925.
A facial hydrothermal method is applied to synthesize Bismuth subcarbonate (Bi2O2CO3, BOC) with controllable defect density (named BOC- X) using sodium bismuthate (NaBiO3) and graphitic carbon nitride (GCN) as precursors. The defects of BOC- X may originate from the extremely slow decomposition of GCN during the hydrothermal process. The BOC- X with optimal defect density shows a photocatalytic nitrogen fixation amount of 957 μmol L-1 under simulated sunlight irradiation within 4 h, which is 9.4 times as high as that of pristine BOC. This superior photocatalytic performance of BOC- X is attributed to the surface defect sites. These defects in BOC- X contribute to a defect level in the forbidden band, which extends the light-harvest region of the photocatalyst from the ultraviolet to the visible-light region. Besides, surface defects prevent electron-hole recombination by accommodating photogenerated electrons in the defect level to promote the separation efficiency of charge carrier pairs. This work not only demonstrates a novel and scalable strategy to synthesize defective Bi2O2CO3 but also presents a new perspective for the synthesis of photocatalysts with controllable defect density.
Bismuth subcarbonate Decorated Reduced Graphene Oxide Nanocomposite for the Sensitive Stripping Voltammetry Analysis of Pb(II) and Cd(II) in Water
Sensors (Basel) 2020 Oct 26;20(21):6085.PMID:33114759DOI:10.3390/s20216085.
In this paper, Bismuth subcarbonate (BiO)2CO3-reduced graphene oxide nanocomposite incorporated in Nafion matrix ((BiO)2CO3-rGO-Nafion) was synthesized and further applied, for the first time, in the sensitive detection of Pb(II) and Cd(II) by square-wave anodic stripping voltammetry (SWASV). The as-synthesized nanocomposites were characterized by energy-dispersive spectroscopy (EDS), Raman spectroscopy, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). (BiO)2CO3 composite plays a key role in the improvement of the detection sensitivity, which can form multicomponent alloy with cadmium and lead. Additionally, the unique structure of rGO can enlarge the surface area and provide abundant active sites. Moreover, Nafion incorporation in the nanocomposite can effectively increase the adhesion and mechanical strength of the film, and further improve the preconcetration ability due to the cation-exchange capacity of its abundant sulfonate groups. As expected, the (BiO)2CO3-rGO/Nafion nanocomposite-modified glassy carbon electrode ((BiO)2CO3-rGO-Nafion/GCE) achieved low detection limits of 0.24 μg/L for Pb(II) and 0.16 μg/L for Cd(II), in the linear range of 1.0-60 μg/L, and showed some excellent performance, such as high stability, good selectivity, and sensitivity. Finally, synthetic water samples were prepared and further used to verify the practicability of the (BiO)2CO3-rGO-Nafion/GCE with satisfactory results.
Controllable Synthesis of Few-Layer Bismuth subcarbonate by Electrochemical Exfoliation for Enhanced CO2 Reduction Performance
Angew Chem Int Ed Engl 2018 Oct 1;57(40):13283-13287.PMID:30129234DOI:10.1002/anie.201807466.
Two-dimensional (2D) engineering of materials has been recently explored to enhance the performance of electrocatalysts by reducing their dimensionality and introducing more catalytically active ones. In this work, controllable synthesis of few-layer Bismuth subcarbonate nanosheets has been achieved via an electrochemical exfoliation method. These nanosheets catalyse CO2 reduction to formate with high faradaic efficiency and high current density at a low overpotential owing to the 2D structure and co-existence of Bismuth subcarbonate and bismuth metal under catalytic turnover conditions. Two underlying fast electron transfer processes revealed by Fourier-transformed alternating current voltammetry (FTacV) are attributed to CO2 reduction at Bismuth subcarbonate and bismuth metal. FTacV results also suggest that protonation of CO2.- is the rate determining step for bismuth catalysed CO2 reduction.